10.15¶
设一系统状态完全由独立参数 \(\vec{x} = (x_1, x_2, \ldots, x_n)\) 确定,并用 \(f(\vec{x})\) 表示某一态函数,则微分
\[ \mathrm{d} f = \sum_{i=1}^n \frac{\partial f}{\partial x_i} \mathrm{d} x_i \]
是恰当微分(exact differential)。如果系统状态由 \(\vec{x}_i \to \vec{x}_f\),则态函数
\[ \Delta f = \int_{\vec{x}_i}^{\vec{x}_f} \mathrm{d} f = f(\vec{x}_f) - f(\vec{x}_i) \]
恰当微分
\[ \mathrm{d} f = \frac{\partial f}{\partial x} \mathrm{d} x + \frac{\partial f}{\partial y} \mathrm{d} y \]
偏导次序可交换:
\[ \frac{\partial^2 f}{\partial x \partial y} = \frac{\partial^2 f}{\partial y \partial x} \]
这与 Maxwell 关系有关。
不恰当微分(inexact differential):
\[ \mathrm{d}\kern{-4.3pt}\bar{\small\phantom{q}}\kern{-0.7pt} g = y \mathrm{d} x \]
可逆性¶
牛顿力学是可逆的
正过程:\(t: 0 \to t\)